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"en": "Pauna, Souza Filho, Kulse, Jovičević-Klug, Springer, Huttula, Fabritius, Raabe: In Situ Observation of Sustainable Hematite–Magnetite–Wüstite–Iron Hydrogen Plasma Reduction",
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"en": "<jats:title>Abstract</jats:title>\n <jats:p>Hydrogen plasma smelting reduction (HPSR) is an energy efficient, electrified, and fast process route to reduce not only iron ores but also thermally stable oxide materials, such as steelmaking sidestreams, waste, lean metallic ores, and metals with strong oxygen bonds. Both basic research of the underlying redox reaction mechanisms and upscaling and piloting of HPSR has gained significant momentum during the past decade, shedding light on reaction kinetics, hydrogen utilization, and process optimization. Yet, many questions still remain unanswered, the most important of which are how the reduction actually works at the interface between the hydrogen plasma and the oxidic and metal melts and what the actual radical species distribution is at the interface. Here, we present for the first time an <jats:italic>in situ</jats:italic> observation series of hematite reduction to metallic iron with filtered plasma imaging and optical emission spectroscopy. With the aid of plasma imaging and the optical spectra, the hematite, magnetite, wüstite, and both near-complete and complete metallization phases could be identified. The atomic hydrogen, iron, and aluminum species together with molecular optical emissions of FeO molecules were used to further analyze the process. Here, we study specifically hematite reduction to metallic iron at 10 pct H<jats:sub>2</jats:sub>/90 pct Ar in 450 and 900 mbar, and at 20 pct H<jats:sub>2</jats:sub>/80 pct Ar in 450 mbar as a model system.</jats:p>",
"fi": "<jats:title>Abstract</jats:title>\n <jats:p>Hydrogen plasma smelting reduction (HPSR) is an energy efficient, electrified, and fast process route to reduce not only iron ores but also thermally stable oxide materials, such as steelmaking sidestreams, waste, lean metallic ores, and metals with strong oxygen bonds. Both basic research of the underlying redox reaction mechanisms and upscaling and piloting of HPSR has gained significant momentum during the past decade, shedding light on reaction kinetics, hydrogen utilization, and process optimization. Yet, many questions still remain unanswered, the most important of which are how the reduction actually works at the interface between the hydrogen plasma and the oxidic and metal melts and what the actual radical species distribution is at the interface. Here, we present for the first time an <jats:italic>in situ</jats:italic> observation series of hematite reduction to metallic iron with filtered plasma imaging and optical emission spectroscopy. With the aid of plasma imaging and the optical spectra, the hematite, magnetite, wüstite, and both near-complete and complete metallization phases could be identified. The atomic hydrogen, iron, and aluminum species together with molecular optical emissions of FeO molecules were used to further analyze the process. Here, we study specifically hematite reduction to metallic iron at 10 pct H<jats:sub>2</jats:sub>/90 pct Ar in 450 and 900 mbar, and at 20 pct H<jats:sub>2</jats:sub>/80 pct Ar in 450 mbar as a model system.</jats:p>",
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"en": "Shelyug, Pauna, Springer, Souza Filho: Puppet Strings of Hydrogen Plasma Reduction of Iron Ores: The Impact of Process Parameters on Plasma Properties and Reduction Kinetics",
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"en": "<jats:title>Abstract</jats:title>\n <jats:p>The reduction effect of plasma in the arc reactor under varying pressure (300–900 mbar), arc current (100–300 A), and electrode-to-sample distances (5–20 mm) was studied utilizing magnetite (Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>) as a model material. Thermodynamic modeling and experimental results revealed that higher pressures improved metallic yield by reducing iron evaporation, achieving up to 89.4 pct reduction at 900 mbar. Kinetic analysis demonstrated rapid magnetite reduction to wüstite within the first 5 minutes and stabilization of metallic iron formation after 15 minutes, with higher currents expediting reduction but increasing energy demand. Plasma characterization via optical emission spectroscopy confirmed the hydrogen utilization efficiency by studying effects of Fe, H, Ar, and Na emissions on plasma behavior and process dynamics, including phenomena like double arcing and contamination from crucible materials. Energetic efficiency peaked at 900 mbar, 200 A, and 10 mm ACD, balancing metal yield and energy consumption.</jats:p>",
"fi": "<jats:title>Abstract</jats:title>\n <jats:p>The reduction effect of plasma in the arc reactor under varying pressure (300–900 mbar), arc current (100–300 A), and electrode-to-sample distances (5–20 mm) was studied utilizing magnetite (Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>) as a model material. Thermodynamic modeling and experimental results revealed that higher pressures improved metallic yield by reducing iron evaporation, achieving up to 89.4 pct reduction at 900 mbar. Kinetic analysis demonstrated rapid magnetite reduction to wüstite within the first 5 minutes and stabilization of metallic iron formation after 15 minutes, with higher currents expediting reduction but increasing energy demand. Plasma characterization via optical emission spectroscopy confirmed the hydrogen utilization efficiency by studying effects of Fe, H, Ar, and Na emissions on plasma behavior and process dynamics, including phenomena like double arcing and contamination from crucible materials. Energetic efficiency peaked at 900 mbar, 200 A, and 10 mm ACD, balancing metal yield and energy consumption.</jats:p>",
"und": "<jats:title>Abstract</jats:title>\n <jats:p>The reduction effect of plasma in the arc reactor under varying pressure (300–900 mbar), arc current (100–300 A), and electrode-to-sample distances (5–20 mm) was studied utilizing magnetite (Fe<jats:sub>3</jats:sub>O<jats:sub>4</jats:sub>) as a model material. Thermodynamic modeling and experimental results revealed that higher pressures improved metallic yield by reducing iron evaporation, achieving up to 89.4 pct reduction at 900 mbar. Kinetic analysis demonstrated rapid magnetite reduction to wüstite within the first 5 minutes and stabilization of metallic iron formation after 15 minutes, with higher currents expediting reduction but increasing energy demand. Plasma characterization via optical emission spectroscopy confirmed the hydrogen utilization efficiency by studying effects of Fe, H, Ar, and Na emissions on plasma behavior and process dynamics, including phenomena like double arcing and contamination from crucible materials. Energetic efficiency peaked at 900 mbar, 200 A, and 10 mm ACD, balancing metal yield and energy consumption.</jats:p>"
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"fi": "Tämä aineisto on saatavilla Kielipankin latauspalvelussa.\n\nSapu-korpus on sosiolingvistinen 2000-luvun satakuntalaista puhekieltä edustava korpus (laajemmin nykysuomalaista puhekieltä edustava korpus), joka on lemmatisoitu sekä annotoitu morfologisesti ja syntaktisesti. Aineisto on kerätty vanhalta murrerajavyöhykkeeltä, jota on halkonut vanhastaan yksi suomen vahvimmista murrerajoista.\nKorpuksessa on 40 tietuetta, jotka edustavat kuuden paikkakunnan puhekieltä (Rauma, Honkilahti, Luvia; Pori, Ulvila-Nakkila, Kokemäki).\nTietueet koostuvat äänitteistä ja niitä vastaavista litteraateista. Äänitteiden yhteiskesto on 37 tuntia ja 3 minuuttia (2223 minuuttia). Informantteja on mukana 51.\nKorpus on osa laajempaa Sapu-aineistoa, joka koostuu yli 262 tunnista äänitteitä ja 213 tunnista suomalais-ugrilaisella tarkekirjoituksella transkriboituja litteraatteja. Keruu on toteutettu vuosina 2007–2019. Sapu-aineistossa on äänitteitä ja litteraatteja 16:lta rajavyöhykkeen paikkakunnalta eri-ikäisiltä ja eritaustaisilta puhujilta. Annotoituun korpukseen päätyneet otokset ovat peräisin vuosilta 2007-2013, ja niissä on edustettuina eri-ikäisten puhujien nykykieltä vanhan murrerajan lounaismurteiselta puolelta (Rauma, Honkilahti, Luvia) ja hämäläisvaikutteiselta siirymurteiselta puolelta (Pori, Ulvila-Nakkila, Kokemäki). Mukana on kaupunkilaisten ja maaseutulaisten kieltä. Aineistoa ja korpusta on hyödynnetty murteentutkimuksen, sosiolingvistiikan, vuorovaikutuslingvistiikan, vuorovaikutussosiolingvistiikan ja kansanlingvistiikan sekä havaintodialektologian alaan kuuluvissa opinnäytteissä ja julkaisuissa.\nHuomaa, että aineiston eri versioissa on mukana henkilötietoja. Henkilötietojen käsittelyssä on noudatettava aineistokohtaisia tietosuojaehtoja.\nAineiston tästä ja muista versioista löytyy tietoja aineistoryhmän sivulta, ks. http://urn.fi/urn:nbn:fi:lb-2025091122.\nTämän aineistoversion lisenssi: http://urn.fi/urn:nbn:fi:lb-2022092123.\nYleiskuvaus korpuksesta löytyy esimerkiksi seuraavasta julkaisusta:\nKurki, Tommi, Huhtala, Atte, Koivunen, Tomi & Mäkitalo, Nelli (2022). Satakuntalaisuus puheessa -korpus ja siitä tehtyjä synkretismihavaintoja: Syncretism in Colloquial Finnish – Observations of the Satakunta corpus. AFinLA-teema, 14, pp. 103-134. doi:10.30660/afinla.111247"
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"en": "The file includes supplementary data for \"Enabling Dynamic Indoor Localization by Employing Intersection over Union as a Metric\". If you would like to re-use the software provided please cite the two following items.\r\n\r\n- Klus, Lucie, Roman Klus, Joaquín Torres-Sospedra, Elena Simona Lohan, Ivo Silva, Cristiano Pendão, and Mikko Valkama. \"Enabling Dynamic Indoor Localization by Employing Intersection over Union as a Metric.\" In 2024 IEEE 100th Vehicular Technology Conference (VTC2024-Fall), pp. 1-7. IEEE, 2024.\r\n\r\n- This Zenodo package: L. Klus et al. (2025). Supplementary materials for “Enabling Dynamic Indoor Localization by Employing Intersection over Union as a Metric”. version v1, 30.01.2025, [Online]. Available: https://doi.org/10.5281/zenodo.11016091\r\n\r\nIf you have any questions about this package, please do not hesitate to contact Lucie Klus (lucie.klus@tuni.fi or llucie.kklus@gmail.com)"
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