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"en": "Putaala, Pauna, Javed, Manzoor, Klapproth, Visuri, Malfliet, Kallio, Souza Filho, Lindgren, Raabe, Fabritius: Hematite Leach Residue as a Material for Hydrogen Plasma Smelting Reduction: A Laboratory-Scale Study on Chemical Composition and Optical Emissions",
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"en": "<jats:title>Abstract</jats:title>\n <jats:p>\n To cut down the intensive\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {CO}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>CO</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n emissions of the steel industry, hydrogen plasma smelting reduction (HPSR) has been suggested as a new method for ore-based steelmaking. Previous research has shown the usability of optical emission spectroscopy (OES) to monitor the process in real time. This study focuses on the connection between the chemical composition of the HPSR-processed hematite leach residue—a sidestream material—and the OES data. A theoretical metallization degree of 87 pct was achieved after 10 minutes of processing with Ar-10-pct\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {H}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>H</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n plasma, but because of evaporation, the actual amount of Fe obtained is lower. A wüstite phase and two spinel phases resembling hercynite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeAl}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeAl</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) and chromite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeCr}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeCr</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) were distinguished from the slag. The emission line intensities and, therefore, the evaporation of the elements from the slag mostly increased with time, showing the enrichment of these elements as Fe reduced. Aluminum evaporation increased most notably, indicating its potential in estimating the state of the reduction process. The results support the suitability of hematite leach residue for HPSR and show how the optical intensities are connected to changes in chemical composition, which can potentially be utilized when scaling up the process.\n </jats:p>",
"fi": "<jats:title>Abstract</jats:title>\n <jats:p>\n To cut down the intensive\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {CO}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>CO</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n emissions of the steel industry, hydrogen plasma smelting reduction (HPSR) has been suggested as a new method for ore-based steelmaking. Previous research has shown the usability of optical emission spectroscopy (OES) to monitor the process in real time. This study focuses on the connection between the chemical composition of the HPSR-processed hematite leach residue—a sidestream material—and the OES data. A theoretical metallization degree of 87 pct was achieved after 10 minutes of processing with Ar-10-pct\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {H}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>H</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n plasma, but because of evaporation, the actual amount of Fe obtained is lower. A wüstite phase and two spinel phases resembling hercynite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeAl}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeAl</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) and chromite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeCr}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeCr</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) were distinguished from the slag. The emission line intensities and, therefore, the evaporation of the elements from the slag mostly increased with time, showing the enrichment of these elements as Fe reduced. Aluminum evaporation increased most notably, indicating its potential in estimating the state of the reduction process. The results support the suitability of hematite leach residue for HPSR and show how the optical intensities are connected to changes in chemical composition, which can potentially be utilized when scaling up the process.\n </jats:p>",
"und": "<jats:title>Abstract</jats:title>\n <jats:p>\n To cut down the intensive\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {CO}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>CO</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n emissions of the steel industry, hydrogen plasma smelting reduction (HPSR) has been suggested as a new method for ore-based steelmaking. Previous research has shown the usability of optical emission spectroscopy (OES) to monitor the process in real time. This study focuses on the connection between the chemical composition of the HPSR-processed hematite leach residue—a sidestream material—and the OES data. A theoretical metallization degree of 87 pct was achieved after 10 minutes of processing with Ar-10-pct\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {H}_2$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:msub>\n <mml:mtext>H</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n plasma, but because of evaporation, the actual amount of Fe obtained is lower. A wüstite phase and two spinel phases resembling hercynite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeAl}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeAl</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) and chromite (\n <jats:inline-formula>\n <jats:alternatives>\n <jats:tex-math>$$\\text {FeCr}_2\\text {O}_4$$</jats:tex-math>\n <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\">\n <mml:mrow>\n <mml:msub>\n <mml:mtext>FeCr</mml:mtext>\n <mml:mn>2</mml:mn>\n </mml:msub>\n <mml:msub>\n <mml:mtext>O</mml:mtext>\n <mml:mn>4</mml:mn>\n </mml:msub>\n </mml:mrow>\n </mml:math>\n </jats:alternatives>\n </jats:inline-formula>\n ) were distinguished from the slag. The emission line intensities and, therefore, the evaporation of the elements from the slag mostly increased with time, showing the enrichment of these elements as Fe reduced. Aluminum evaporation increased most notably, indicating its potential in estimating the state of the reduction process. The results support the suitability of hematite leach residue for HPSR and show how the optical intensities are connected to changes in chemical composition, which can potentially be utilized when scaling up the process.\n </jats:p>"
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"fi": "Työolobarometrit selvittävät suomalaisen työelämän laatua ja työolojen muutosta palkansaajien näkökulmasta. Työolobarometrien sisältö on pysynyt pääosin samanlaisena eri vuosina. Vuoden 2023 aineistossa kysyttiin aluksi vastaajien työpaikan henkilöstön määrästä sekä esitettiin väitteitä työilmapiiristä, työkyvyn ylläpitämisestä, avoimuudesta ja tasapuolisuudesta työpaikalla. Kysyttiin myös, vaikutetaanko työpaikalla osaamisen kehittämiseen ja työympäristön turvallisuuteen. Edelleen kartoitettiin työntekijöiden mahdollisuuksia kouluttautumiseen ja uuden oppimiseen. Seuraavaksi kysyttiin työajan joustoista, etätyöstä, palkkauksesta ja digitaalisista työvälineistä. Lisäksi selvitettiin työntekijän vaikutusmahdollisuuksia esimerkiksi työnjakoon, työtahtiin, työskentelypaikkaan tai työpaikan toiminnan kehittämiseen. Vastaajat kertoivat digitaalisten työvälineiden, esimerkiksi sosiaalisen median, erilaisten pikaviestinten ja tekoälyyn perustuvien välineiden käytöstä. Edelleen kartoitettiin, ilmeneekö vastaajan työpaikalla eriarvoista kohtelua, syrjintää tai henkistä väkivaltaa eri tahoilta liittyen esimerkiksi etniseen taustaan, sukupuoleen tai ikään. Lisäksi kysyttiin fyysisen väkivallan ja seksuaalisen häirinnän kohtaamisesta. Kartoitettiin myös työkykyyn ja työhön liittyviä tuntemuksia kuten stressiä, uupumusta, innostusta ja yhteisöllisyyttä. Edelleen käsiteltiin työn kuormittavuutta ja vastaajan oman työpaikan säilymisen varmuutta. Lopuksi kysyttiin kuulumisesta ammattiliittoon ja työttömyyskassaan sekä kilpailukieltosopimuksesta. Taustamuuttujina olivat muiden muassa sukupuoli, ikä, ammattiasema, työnantajatyyppi, työsuhteen pysyvyys ja kesto, työn koko- tai osa-aikaisuus, työpaikan toimiala ja työaika."
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"en": "This dataset studied notions that disabled or chronically ill people in Finland had concerning freedom. The study aimed to find out how a possible illness or disability affected feelings and experiences with regard to freedom in life. The data contain 11 transcribed interviews. The study was funded by the Sokra project of the National Institute for Health and Welfare (THL) to coordinate the promotion of social inclusion. In the data, the interviewees shared how their disability or illness affected their everyday lives. They were asked what sort of meanings the interviewees gave to freedom and whether they considered their lives to have freedom. The interviews also discussed, for instance, whether the disability or illness had set limitations or challenges on the participants' lives, future plans or dreams. In addition, experiences were discussed regarding, for instance, schools, health care services and other institutions, and receiving sufficient support and assistance. Additionally, topics covered services, peer support, feelings of being heard, and friends and relatives' attitudes toward getting a diagnosis. Background information included date, gender, age and the illness/disability in question (e.g. epilepsy, cerebral palsy). The data were organised into an HTML index at FSD. The dataset is only available in Finnish.",
"fi": "Aineisto käsittelee somaattisesti pitkäaikaissairaiden ja fyysisesti vammaisten alle 30-vuotiaiden vapaudelle antamia merkityksiä. Aihetta käsitellään monesta näkökulmasta haastateltujen koko elämänkaaren ajalta sekä tulevaisuudennäkymien kautta. Tutkija on pyrkinyt selvittämään, miten mahdollinen sairaus tai vamma vaikuttaa ajatuksiin ja kokemukseen vapaudesta. Aineisto sisältää 11 haastattelua. Tutkimusta on tukenut Terveyden ja hyvinvoinnin laitoksen (THL) Sosiaalisen osallisuuden edistämisen koordinaatiohanke (Sokra). Haastatellut kuvailevat aineistossa sitä, millaisia oireita sairaus tai vamma aiheuttaa ja miten oireet näkyvät heidän arjessaan. Haastattelussa kysytään millaisia merkityksiä vastaajat antavat vapaudelle ja toteutuuko vapaus heidän elämässään. Haastatteluissa keskusteltiin muun muassa siitä, onko sairaus tai vamma asettanut rajoitteita tai haasteita elämälle, tulevaisuuden suunnitelmille tai haaveille. Lisäksi käsitellään sitä, millaisia kokemuksia haastateltavilla on esimerkiksi kouluista, terveydenhuollosta ja muista yhteiskunnan instituutioista sekä tarvittavan avun ja tuen saamisesta. Myös esimerkiksi palvelujen toimivuudesta, vertaistuen merkityksestä, kuulluksi tulemisen kokemuksesta ja lähipiirin suhtautumisesta diagnoosin saamiseen keskustellaan. Taustatietoina aineistossa on haastatteluaika, haastateltavan sukupuoli ja ikä sekä haastateltavan sairaus tai vamma, esimerkiksi epilepsia tai CP-vamma. Aineistosta on tehty html-versio, jonka hakemiston avulla haastatteluja on helppo selata."
},
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"id": "eb6d49d6-6bfc-4d8c-86b8-d9497924b295",
"url": "http://www.yso.fi/onto/okm-tieteenala/ta5",
"in_scheme": "http://www.yso.fi/onto/okm-tieteenala/conceptscheme",
"pref_label": {
"en": "Social sciences",
"fi": "YHTEISKUNTATIETEET",
"sv": "Samhällsvetenskaper"
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},
{
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"url": "http://www.yso.fi/onto/okm-tieteenala/ta3",
"in_scheme": "http://www.yso.fi/onto/okm-tieteenala/conceptscheme",
"pref_label": {
"en": "Medical and health sciences",
"fi": "LÄÄKE- JA TERVEYSTIETEET",
"sv": "Medicin och hälsovetenskaper"
}
}
],
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"issued": "2019-08-14",
"keyword": [
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"fyysinen toimintakyky",
"elämänhallinta",
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"chronic illness",
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In addition, the dataset includes model output files: the f(X,N,B) correction factor as a function of number of adsorbed water monolayers for selected particle sizes and FHH B parameter values; a comparison table of experimental and modelled critical supersaturation values with their ratios across the full diameter range for all 12 substances; the critical supersaturation as a function of number of adsorbed layers at activation for four FHH correction methods; and the number of adsorbed layers at activation as a function of particle diameter for all 12 substances.\n\n**CONTENTS**\n\n**1. Cloud condensation activation measurements**\n\nFolder: **CCN\\_activation\\_data.zip**\n\nThis dataset contains cloud condensation nuclei activation data reporting the critical supersaturation (S\\*) at which 50% of particles activate as cloud droplets as a function of dry particle diameter.\n\nEach file corresponds to a specific material `*_AAC_50.txt` and contains:\n\n* **Dp**: Dry particle diameter (nm)\n* **dDp**: Uncertainty in dry particle diameter (nm)\n* **S\\*:** Critical supersaturation at 50% activation. (P/P0 -1)\n* **dS:** Measurement uncertainty in S\\*\n\n**2. Water and Nitrogen adsorption isotherm measurements**\n\nFolders: **H2O isotherms.zip** and **N2\\_isotherms.zip**\n\nThe dataset includes nitrogen adsorption isotherms (adsorption branch, `*_N2_N_ad.dat`) and water adsorption isotherms (desorption branch, `*_H2O_N_de.dat`). Each file contains a header with references to the original experimental filenames and data in two columns:\n\n* **P/P0**: Saturation ratio\n* **N\\_ads (N\\_des)**: Number of adsorbed water or nitrogen monolayers in the adsorption (desorption) branch\n\n**3. MODEL OUTPUT AND COMPARISON DATA**\n\n**3.1 SSw\\_comparison\\_table.csv**\n\nData for Figures 1 and 3a.\n\nCritical supersaturation (SSw, %) for all 12 substances across a particle diameter grid of 40-1000 nm.\n\nContains experimental SSw values with uncertainties, model estimates from three FHH-based parameterisations (original, size-corrected, and size+fractal-corrected), the Kelvin-equation reference curve, and the ratios of modelled to experimental SSw. Rows where no experimental measurement exists at a given diameter contain model values only.\n\n* **Substance**: sample identifier\n* **Dp (nm)**: particle diameter (nm)\n* **dDp (nm)**: uncertainty in particle diameter (nm)\n* **SSw\\_exp**: experimental critical supersaturation (%)\n* **dSSw\\_exp**: uncertainty in experimental SSw (%)\n* **SSw\\_kelvin**: Kelvin-equation SSw (%) — pure water limit\n* **Ssw\\_FHH**: modelled SSw (%) — FHH original\n* **SSw\\_FHH(D)**: modelled SSw (%) — FHH with size correction\n* **SSw\\_FHH(D,f)**: modelled SSw (%) — FHH with size and fractal correction\n* **ratio\\_SSw\\_FHH**: SSw\\_FHH / SSw\\_exp\n* **ratio\\_SSw\\_FHH(D)**: SSw\\_FHH(D) / SSw\\_exp\n* **ratio\\_SSw\\_FHH(D,f)**: SSw\\_FHH(D,f) / SSw\\_exp\n* **data\\_type**: \"experimental + model\" or \"model only\"\n\n**3.2 fXNB\\_data.csv**\n\nData for Figure 2.\n\nTheoretical f(X,N,B) correction factor as a function of number of adsorbed water monolayers N (range 1-2000), computed for three particle diameters (10, 100, 1000 nm) and three FHH B parameter values (1.01, 2, 3).\n\n* **Diameter\\_nm** : dry particle diameter (nm)\n* **B\\_value**: FHH B parameter\n* **N\\_mono**: number of adsorbed water monolayers\n* **fXNB**: f(X,N,B) correction factor (dimensionless, 0-1)\n\n**3.3 SSw\\_vs\\_N.csv**\n\nData for Figure 3b.\n\nCritical supersaturation SSw (%) as a function of number of adsorbed water layers N at activation, for four correction methods applied to K-Feldspar (diameter = 300 nm, A = 3.46, B = 2.14, B\\_corr = 1.06). N range: 10-10000.\n\n* **Method**: correction method (Uncorrected, Size\\_corrected, Fractal\\_corrected, Size\\_and\\_fractal\\_corrected)\n* **N**: number of adsorbed water monolayers at activation\n* **SSw**: critical supersaturation (%)\n\n**3.4 N\\_vs\\_diameter.csv**\n\nData for Figure 3c.\n\nNumber of adsorbed water layers N at CCN activation as a function of particle diameter, for all 12 metal oxide and mineral substances. Diameter range: 40-1000 nm. N range: 10-2000.\n\n* **Substance**: sample identifier\n* **Diameter\\_nm**: particle diameter (nm)\n* **N**: number of adsorbed water layers at critical supersaturation\n\n**NOTES**\n\n- *NA* indicates missing or not applicable values (e.g., experimental columns for model-only rows, ratio values where no experimental reference exists, or model values that did not converge). \n- File headers within each CSV provide additional metadata, including column descriptions."
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